To be a little more elaborate, I'll include the material produced by the e-cells during their respective period in the growth cycle.
periostracial (conchiolin) -> prismatic (calcite) -> nacreous (aragonite)
Not all mollusks though. In the case of scallops or some gastropods it's:
periostracial (conchiolin) -> prismatic (calcite) -> foliated (calcite)
In nautilus and other gastropods it's:
periostracial (conchiolin) -> prismatic (calcite) -> columnar (aragonite)
Technically, there's actually four layers, but only in over-mature shells. Pearls are harvested young.
periostracial (conchiolin) -> prismatic (calcite) -> nacreous (aragonite) -> calcitic (calcite)